Role of anion•••π interactions in photochemical [2+2] cycloaddition reaction
Singh, Ashutosh Sharan (2025). Role of anion•••π interactions in photochemical [2+2] cycloaddition reaction. oai:ojs2.pubs.rsyn.org:article/138
Singh, Ashutosh Sharan. "Role of anion•••π interactions in photochemical [2+2] cycloaddition reaction.".
Singh, Ashutosh Sharan. "Role of anion•••π interactions in photochemical [2+2] cycloaddition reaction.".
@article{singh2025role,
title = {Role of anion•••π interactions in photochemical [2+2] cycloaddition reaction},
author = {Singh, Ashutosh Sharan},
year = 2025,
journal = {},
url = oai:ojs2.pubs.rsyn.org:article/138,
language = en
}
TY - JOUR TI - Role of anion•••π interactions in photochemical [2+2] cycloaddition reaction AU - Singh, Ashutosh Sharan PY - 2025 DA - 2025-04-07 UR - oai:ojs2.pubs.rsyn.org:article/138 AB - Inspired by biological processes, anion•••π interactions1 have been explored in multidisciplinary areas of research such as recognition and sensing2, catalysis3, etc. Because of the weak nature of anion•••π interactions, such interaction is still a challenging task to explore in an artificial system, especially in a polar solvent(s). In this presentation, we will discuss the role of the anion (as template) in photochemical [2+2] cycloaddition reaction through anion•••π interactions to form a four-membered cyclic ring. The hydrogen atom of such a four-membered ring is very sensitive to pH and temperature. The main problem is the removal of the template after the photochemical [2+2] cycloaddition reaction. Anion (as a template) can be removed easily. The complete process and role of anion•••π interactions will be discussed in the present conference. Keywords: Anion•••π interactions, photochemical [2+2] cycloaddition reaction, hydrogen-bond. LA - en ER -
🤖 AI Key Takeaways & Research Insights
Automated AI Analysis💡 Core Finding
Inspired by biological processes, anion•••π interactions1 have been explored in multidisciplinary areas of research such as recognition and sensing2, catalysis3, etc.
🔬 Methodology
Because of the weak nature of anion•••π interactions, such interaction is still a challenging task to explore in an artificial system, especially in a polar solvent(s).
🎯 Domain Impact
Keywords: Anion•••π interactions, photochemical [2+2] cycloaddition reaction, hydrogen-bond.
Abstract
Inspired by biological processes, anion•••π interactions1 have been explored in multidisciplinary areas of research such as recognition and sensing2, catalysis3, etc. Because of the weak nature of anion•••π interactions, such interaction is still a challenging task to explore in an artificial system, especially in a polar solvent(s). In this presentation, we will discuss the role of the anion (as template) in photochemical [2+2] cycloaddition reaction through anion•••π interactions to form a four-membered cyclic ring. The hydrogen atom of such a four-membered ring is very sensitive to pH and temperature. The main problem is the removal of the template after the photochemical [2+2] cycloaddition reaction. Anion (as a template) can be removed easily. The complete process and role of anion•••π interactions will be discussed in the present conference. Keywords: Anion•••π interactions, photochemical [2+2] cycloaddition reaction, hydrogen-bond.
Full text is available at the publisher's website.
Read Full Article ↗